certain / specific
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certainly
Used as an adverb to express certainty or a high probability; synonymous with 'sicherlich' (certainly) or 'gewiss' (surely).
Sie hat so viel gelernt, sie besteht die Prüfung bestimmt.
She studied so much; she'll certainly pass the exam.
'Bestimmt' is the past participle of the verb 'bestimmen' (to determine, to define). This origin helps explain the meanings: something is already determined, certain, or intended for a purpose.
Wir müssen noch den genauen Zeitpunkt für das Treffen bestimmen.
We still have to determine the exact time for the meeting.
As an adverb (meaning: certainly), 'bestimmt' is not declined. As an adjective (meaning: specific), it stands before a noun and takes an ending.
Das wird bestimmt ein schöner Abend.
That will certainly be a nice evening.
In the meaning 'vorgesehen für' (intended for), 'bestimmt' is always used with the preposition 'für' (for) and the accusative. The structure is: something is intended for someone/something.
Diese Plätze sind für Gäste mit Behinderung bestimmt.
These seats are intended for guests with disabilities.
maybe
'vielleicht' and 'bestimmt' are opposites when talking about how likely something is. 'vielleicht' shows uncertainty: something is possible, but not clear. 'bestimmt', on the other hand, shows great certainty or a strong expectation. If you want to stay cautious, 'vielleicht' fits. If you are almost sure, 'bestimmt' sounds more natural.
Die Gruppe findet bestimmt eine Lösung für das Problem.
The group will certainly find a solution to the problem.
Maria kauft vielleicht noch Brot, wenn der Laden offen ist.
Maria might buy some bread if the shop is open.